Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Hydrochloric Acid → Meso-Tartaric acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Hydrochloric Acid | HCID 313 | — |
| 반응물 | Sodium Chloride | HCID 5234 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | D-Tartaric acid | HCID 439655 | — |
| 반응물 | L-Tartaric acid | HCID 444305 | — |
| 촉매 | Iron | HCID 23925 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Meso-Tartaric acid | HCID 447315 | — |
반응 단계
A mesotartaric acid containing treatment solution was prepared by heating a solution of 95 g L(+)-tartaric acid, also known as d-tartaric acid, in 1 kg of aqueous 30% w/w NaOH at 118° C. for two hours. After cooling to room temperature, HCl-solution was added to adjust the pH to 6. Depending on the amount and the type of HCl solution used, NaCl or water was added in order to obtain a solution containing 20% w/w of NaCl. Hereafter FeCl2 was added in such an amount that the solution contained 4.8 g Fe″ per 25.5 g of (meso)tartaric acid. In the resulting treatment solution 29.8% w/w of the original L(+)-tartaric acid was transformed into the meso form.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06800263B1 |
| 출처 데이터셋 | uspto-grants-2004_10 |
| ORD ID | ord-c585a21b8dbb4a80a4dd0c135d175c20 |
| 출처 메모 | uspto-grants-2004_10 |