Sulfuryl chloride → HCID 86762023, 화합물

HRID 39247노트

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HRID 39247 반응식
S(Cl)([Cl:4])(=O)=O.[C:6](=[O:35])([O:10][CH:11]([O:13][C:14](=[O:34])[CH2:15][CH2:16][CH:17]([P:26]([O:31][CH2:32][CH3:33])([O:28][CH2:29][CH3:30])=[O:27])[P:18]([O:23][CH2:24][CH3:25])([O:20][CH2:21][CH3:22])=[O:19])[CH3:12])SCC>C(Cl)Cl>[CH2:21]([O:20][P:18]([CH:17]([P:26]([O:31][CH2:32][CH3:33])([O:28][CH2:29][CH3:30])=[O:27])[CH2:16][CH2:15][C:14]([O:13][CH:11]([O:10][C:6]([Cl:4])=[O:35])[CH3:12])=[O:34])([O:23][CH2:24][CH3:25])=[O:19])[CH3:22]

참가 물질

4

반응물 2

HCID 24648Sulfuryl chlorideHCID 86762024S-Ethyl O-1-(4,4-bis(diethylphosphono)butanoyloxy)ethyl carbonothioate

생성물 1

HCID 86762023HCID 86762023, 화합물

시약·촉매·용매 1

HCID 6344Dichloromethane용매

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온도
0 °C

실험 절차

Sulfuryl chloride (78 μL, 0.96 mmol) was added drop-wise to a solution of 23 (237 mg, 0.48 mmol) in 10 mL of CH2Cl2 cooled to 0° C. The solution was stirred for 2 h. The solvent was removed under reduced pressure to afford chloroformate 24 and which was used for the next reaction without further purification.

후처리

  1. customThe solvent was removed under reduced pressure

출처 및 근거

ORD 기록
ord-6e28a8d386fe456a9190bdf5a12e38f0
출처 데이터셋
uspto-grants-2013_09
특허 번호
US08524691B2

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