참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 4-Methylmorpholine | HCID 7972 | — |
| 반응물 | Phosphorodichloridic acid, hexyl ester | HCID 6422909 | — |
| 반응물 | HCID 178520956 | HCID 178520956 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 1,4-Cyclohexanedimethanol | HCID 7735 | — |
반응 단계
Under an argon stream, 10 g of trans-1,4-cyclohexane dimethanol (CHDM), 15.25 mL (14.03 g) of N-methyl morpholine (NMM), and 50 mL of methylene chloride were transferred into a 250 mL flash equipped with a funnel. The solution in the flask was cooled down to −40° C. with stirring. A solution of 15.19 g of hexyl phosphoro-dichloridate (HOP) in 20 mL of methylene chloride was added through the funnel, and an additional 10 mL of methylene chloride was used to flush through the funnel. The mixture was then brought up to room temperature gradually and kept stirring for four hours.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06800672B2 |
|---|
| 출처 데이터셋 | uspto-grants-2004_10 |
|---|
| ORD ID | ord-7a535b7db30c4507abd5eff7afb0fe04 |
|---|
| 출처 메모 | uspto-grants-2004_10 |
|---|
