2-Methoxy-4-nitrophenol acetate → HCID 22646533, 화합물

HRID 393676노트

반응식

HRID 393676 반응식
[C:1]([O:4][C:5]1[CH:10]=[CH:9][C:8]([N+:11]([O-])=O)=[CH:7][C:6]=1[O:14][CH3:15])(=[O:3])[CH3:2]>C(O)C.[Pd]>[C:1]([O:4][C:5]1[CH:10]=[CH:9][C:8]([NH2:11])=[CH:7][C:6]=1[O:14][CH3:15])(=[O:3])[CH3:2]

참가 물질

4

반응물 1

HCID 499852-Methoxy-4-nitrophenol acetate

생성물 1

HCID 22646533HCID 22646533, 화합물수율 95.5%

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 702Ethanol용매

실험 절차

A solution of 4-acetoxy-3-methoxynitrobenzene (8.5 g, 40 mmol) in ethanol (175 ml) containing 10% palladium-on-charcoal catalyst (50% in water, 0.5 g) was stirred under hydrogen at atmospheric pressure for 1.5 hours. The catalyst was removed by filtration and the volatiles were removed by evaporation to give 4-acetoxy-3-methoxyaniline as an oil (6.92 g, 95%).

후처리

  1. customThe catalyst was removed by filtration
  2. customthe volatiles were removed by evaporation

출처 및 근거

ORD 기록
ord-deb6128e0eb74f56a839a4477bb12e27
출처 데이터셋
uspto-grants-2004_10
특허 번호
US06809097B1

반응 노트

불러오는 중…