Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methyl 4-chlorobenzoate → Potassium 4-chlorobenzoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methyl 4-chlorobenzoate | HCID 14307 | — |
| 반응물 | Potassium trimethylsilanolate | HCID 23668039 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | Potassium 4-chlorobenzoate | HCID 23664289 | 84.1% |
반응 단계
The procedure of Example 1 was followed using methyl 4-chlorobenzoate (13.65 g, 80 mmol), potassium trimethylsilanolate (10.26 g, 80 mmol), dry ether (500 mL) and a 4 h reaction time. Potassium 4-chlorobenzoate (13.1 g, 84% yield) was isolated as a white solid: 1H NMR (D2O, DSS, 80 MHz) δ 7.68 ppm (ABq, Δν1-3 =29 Hz, J=8.5 Hz, Ar--H's, 4H). Anal. Calcd. for C7H4ClKO2 : C, 43.19; H, 2.07. Found: C, 43.27; H, 2.33.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04723016 |
| 출처 데이터셋 | uspto-grants-1988_02 |
| ORD ID | ord-ee16a2a12b5a4c94a18c4647c3615c25 |
| 출처 메모 | uspto-grants-1988_02 |