Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Methyl 4-chlorobenzoate → Sodium p-chlorobenzoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Methyl 4-chlorobenzoate | HCID 14307 | — |
| 반응물 | Sodium trimethylsilanolate | HCID 23672319 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | Sodium p-chlorobenzoate | HCID 23691027 | 94.7% |
반응 단계
The procedure of Example 1 was followed using methyl 4-chlorobenzoate (4.55 g, 26.6 mmol), sodium trimethylsilanolate (2.99 g, 26.6 mmol), dry toluene (150 mL), and 4 h of heating at 80°. Sodium 4-chlorobenzoate (4.50 g, 86% yield) was isolated as a white solid: 1H NMR (D2O, DSS, 80 MHz) δ 7.65 ppm (ABq, Δν1-3 =29 Hz, J=8 Hz, Ar--H's, 4H).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04723016 |
| 출처 데이터셋 | uspto-grants-1988_02 |
| ORD ID | ord-4e5e8dfb24b64e2785502aae5a36ffcf |
| 출처 메모 | uspto-grants-1988_02 |