Phthalide → 1,2-Benzenedimethanol
반응식
[C:1]1([C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH2:4][O:3]1)=[O:2].[H][H]>O1CCCC1>[C:5]1([CH2:4][OH:3])[C:10]([CH2:1][OH:2])=[CH:9][CH:8]=[CH:7][CH:6]=1참가 물질
4
실험 절차
Phthalide (5 mmol), a ruthenium complex 1 (0.025 mmol), and tetrahydrofuran (2 mL) were charged into a 100-mL autoclave equipped with a stirrer. Then, the mixture was subjected to hydrogenation at a hydrogen pressure of 5 MPa at 100° C. for 16 hours. The reaction liquid was analyzed by gas chromatography. As a result, 1,2-benzenedimethanol was obtained at a conversion rate of 66% and a selectivity of 99% or more.
후처리
- customequipped with a stirrer
- customThe reaction liquid
출처 및 근거
- ORD 기록
- ord-abdaff8d3dc44bac983ca04b5b92d38e
- 출처 데이터셋
- uspto-grants-2013_09
- 특허 번호
- US08524953B2
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