p-Toluenesulfonic acid → Diisobutylaluminum hydride

HRID 397020노트

반응식

HRID 397020 반응식
[H-].C(O[Al+:7]OCC(C)C)C(C)C.[CH3:13][C:14]1[CH:15]=CC(S(O)(=O)=O)=C[CH:19]=1.Cl[Si](C)(C)[C:26]([CH3:29])([CH3:28])[CH3:27].C1C=C[NH+]=CC=1.[O-][Cr](Cl)(=O)=O.C1C=CC(N=NC2C=CC(N)=NC=2N)=CC=1.Cl>CO>[CH3:27][CH:26]([CH2:29][AlH:7][CH2:15][CH:14]([CH3:13])[CH3:19])[CH3:28]

참가 물질

7

반응물 5

HCID 6101p-Toluenesulfonic acid2회HCID 8691Phenazopyridine hydrochlorideHCID 28928tert-Butyldimethylsilyl chlorideHCID 22034396HCID 22034396, 화합물HCID 178418287HCID 178418287, 화합물

생성물 1

HCID 14487Diisobutylaluminum hydride

시약·촉매·용매 1

HCID 887Methanol용매2회

실험 절차

diisobutoxyaluminum hydride, pTsOH: p-toluenesulphonic acid, MeOH: methanol, CITBS: chloro-dimethyl-t-butyl silane, PCC: pyridium chlorochrome, W-K: Wolff-Kishiner reduction.

출처 및 근거

ORD 기록
ord-7f5340b852f3480c8a70a2fbafd9f35a
출처 데이터셋
uspto-grants-2003_08
특허 번호
US06608215B2

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