Ethyl 2-(4,4-dimethyl-2-cyclohexen-1-ylidene)acetate → HCID 23001036, 화합물

HRID 397718

반응식

HRID 397718 반응식
[CH3:1][C:2]1([CH3:14])[CH2:7][CH2:6][C:5](=[CH:8][C:9]([O:11][CH2:12][CH3:13])=[O:10])[CH:4]=[CH:3]1>CO.[Pd]>[CH3:1][C:2]1([CH3:14])[CH2:3][CH2:4][CH:5]([CH2:8][C:9]([O:11][CH2:12][CH3:13])=[O:10])[CH2:6][CH2:7]1

참가 물질

4

반응물 1

HCID 53954530Ethyl 2-(4,4-dimethyl-2-cyclohexen-1-ylidene)acetate

생성물 1

HCID 23001036HCID 23001036, 화합물수율 91%

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 887Methanol용매

실험 절차

A solution of ethyl 2-(4,4-dimethyl-2-cyclohexene-1-ylidene)acetate (Preparation 13, 4.0 g, 21 mmol) in methanol (40 ml) was treated with 5% palladium on carbon, and the suspension was placed under an atmosphere of hydrogen (60 p.s.i.) at room temperature for 48 h. The mixture was filtered through a short pad of silica (40 g) and the filtrate was concentrated in vacuo to afford the title compound as a colourless oil (3.7 g, 91%).

후처리

  1. filtrationThe mixture was filtered through a short pad of silica (40 g)
  2. concentrationthe filtrate was concentrated in vacuo

출처 및 근거

ORD 기록
ord-1fb8cb4c8fab46169484184badf6d66c
출처 데이터셋
uspto-grants-2003_08
특허 번호
US06610711B2

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