Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Diethylene Glycol Monoethyl Ether → Carbazole-4-carboxamide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Diethylene Glycol Monoethyl Ether | HCID 8146 | — |
| 반응물 | 1,2,3,4-Tetrahydrocarbazole-4-carboxamide | HCID 22738726 | — |
| 촉매 | Palladium | HCID 23938 | — |
| 생성물 | Carbazole-4-carboxamide | HCID 22741084 | — |
반응 단계
A 1,2,3,4-tetrahydrocarbazole-4-carboxamide or 4-carboxhydrazide (13) is dehydrogenated by refluxing in a solvent such as carbitol in the presence of Pd/C to produce the carbazole-4-carboxamide. Alternately, treatment of (13) with DDQ in an appropriate solvent such as dioxane yields carbozole (14).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06610728B2 |
| 출처 데이터셋 | uspto-grants-2003_08 |
| ORD ID | ord-d758e5a7a8d04027b705df0f6362e8d1 |
| 출처 메모 | uspto-grants-2003_08 |