1(N,N-dimethylaminoethyl)indene → HCID 178483377, 화합물

HRID 398256노트

반응식

HRID 398256 반응식
[CH3:1][N:2]([CH2:4][CH2:5][CH:6]1[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[CH:8]=[CH:7]1)[CH3:3].CN(CCC1CC=CC=1)C.[Cl-:25].[Cl-].[Cl-].[CH:28]1([Zr+3:33])[CH:32]=[CH:31][CH:30]=[CH:29]1.[Cl-].[Cl-].[Cl-].C[Zr](C)(C)(C)(C)C1C=CC=C1>>[Cl-:25].[Cl-:25].[CH3:1][N:2]([CH2:4][CH2:5][CH:6]1[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[CH:8]=[C:7]1[Zr+2:33][CH:28]1[CH:32]=[CH:31][CH:30]=[CH:29]1)[CH3:3]

참가 물질

5

반응물 4

HCID 119880011(N,N-dimethylaminoethyl)indeneHCID 12154709(N,N-dimethylaminoethyl)cyclopentadieneHCID 178477801HCID 178477801, 화합물HCID 178478629HCID 178478629, 화합물

생성물 1

HCID 178483377HCID 178483377, 화합물수율 35%

실험 절차

Example 1 was repeated in the same manner as described except that 1(N,N-dimethylaminoethyl)indene was substituted for (N,N-dimethylaminoethyl)cyclopentadiene and that cyclopentadienylzirconium trichloride was substituted for pentamethylcyclopentadienylzirconium trichloride. The yield was 35.0%. The physical properties of the product are as follows:

출처 및 근거

ORD 기록
ord-3b0cd03279b84492bcc83f1f6706ec1a
출처 데이터셋
uspto-grants-2003_08
특허 번호
US06610872B1

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