1,3-Cyclopentadiene, 5-(1-methylethylidene)- → HCID 131720872, 화합물

HRID 399296

반응식

HRID 399296 반응식
[C:1]1([CH-:7][C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[K+].[CH3:15][C:16]([CH3:22])=[C:17]1[CH:21]=[CH:20][CH:19]=[CH:18]1>C1COCC1>[CH:17]1([C:16]([CH3:22])([CH3:15])[CH:7]([C:8]2[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=2)[C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[CH:21]=[CH:20][CH:19]=[CH:18]1

참가 물질

4

반응물 2

HCID 1374671,3-Cyclopentadiene, 5-(1-methylethylidene)-HCID 11858962Potassium, (diphenylmethyl)-

생성물 1

HCID 131720872HCID 131720872, 화합물

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매2회

반응 조건

온도
25 °C

실험 절차

Potassium diphenylmethanide (5.72 g, 27.8 mmols) in about 50 mL of THF was slowly added to 6,6-dimethylfulvene (2.94 g, 27.8 mmols) in about 100 mL of THF at about 25 C. The reaction mixture was stirred at about 25° C. for about 16 hours. The solvent was removed under reduced pressure to give the desired product as a sticky, oily solid.

후처리

  1. customThe solvent was removed under reduced pressure

출처 및 근거

ORD 기록
ord-977dbb3c7fbe44209e362dc473b9d505
출처 데이터셋
uspto-grants-1998_10
특허 번호
US05817849

연결된 노트

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