Ethyl acetate hexane → (1R,2R)-1,2-Cyclopentanedimethanol

HRID 400226노트

반응식

HRID 400226 반응식
S(OS([O-])(=O)=O)([O-])(=O)=O.[Ce+3].S(OS([O-])(=O)=O)([O-])(=O)=O.S(OS([O-])(=O)=O)([O-])(=O)=[O:21].[Ce+3].C([O:33][CH2:34][CH3:35])(=O)C.[CH3:36][CH2:37][CH2:38][CH2:39][CH2:40]C>>[C@@H:35]1([CH2:34][OH:33])[CH2:36][CH2:37][CH2:38][C@H:39]1[CH2:40][OH:21]

참가 물질

3

반응물 2

HCID 21226206Ethyl acetate hexaneHCID 22269528HCID 22269528, 화합물

생성물 1

HCID 11286477(1R,2R)-1,2-Cyclopentanedimethanol

실험 절차

TLC: Rf =0.25, silica gel, ethyl acetate:hexane (1:1), cerium disulfate.

출처 및 근거

ORD 기록
ord-ec6f098bdb8040888f0bbe38c4b1fa91
출처 데이터셋
uspto-grants-1998_10
특허 번호
US05827868

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