Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
2-Isopropylpyridine → 1-Oxo-2-(propan-2-yl)-1lambda~5~-pyridine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 2-Isopropylpyridine | HCID 69523 | — |
| 반응물 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 1-Oxo-2-(propan-2-yl)-1lambda~5~-pyridine | HCID 13172079 | 85% |
반응 단계
A mixture of isopropylpyridine (2.1 g, 17.75 mmol) and m-CPBA (5.0 g, 1.3 eq.) in CH2Cl2 was stirred overnight at room temperature. Then, the reaction mixture was diluted with CH2Cl2 (twice the volume) and successively washed with aqueous sodium bicarbonate (twice) and brine, dried (Na2SO4) and evaporated to give 2.0 g (85%) of the title compound 104.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08741926B2 |
| 출처 데이터셋 | uspto-grants-2014_06 |
| ORD ID | ord-488d8dc885094e2fb161ff668d22dcab |
| 출처 메모 | uspto-grants-2014_06 |