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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 405650생성일: 2026년 10월 25일

Acrylic Acid → Phenoxyethyl acrylate methyl methacrylate acrylic acid

https://huagongshe.com/reaction/405650

반응식

참여 물질

역할이름HCID투입량
반응물Acrylic AcidHCID 6581—
반응물Methyl MethacrylateHCID 6658—
반응물Phenoxyethyl acrylateHCID 39485—
반응물1,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)HCID 75763—
용매IsopropanolHCID 3776—
용매Methyl Ethyl KetoneHCID 6569—
생성물Phenoxyethyl acrylate methyl methacrylate acrylic acidHCID 86634647—

반응 조건

온도75 °C

반응 단계

360.0 g of methyl ethyl ketone was introduced in a 2 L three-necked flask equipped with a stirrer, a thermometer, a reflux condenser, and a nitrogen gas introduction tube, and was heated to 75° C. Thereafter, while the temperature inside the flask was maintained at 75° C., a mixture solution of 180.0 g of phenoxyethyl acrylate, 162.0 g of methyl methacrylate, 18.0 g of acrylic acid, 72 g of methyl ethyl ketone, and 1.44 g of “V-601” (trade name, manufactured by Wako Pure Chemical Industries Ltd.) was added dropwise into the flask at a constant rate such that the dropwise addition was completed in 2 hours. After the dropwise addition was completed, a solution of 0.72 g of “V-601 (trade name)” and 36.0 g of methyl ethyl ketone was added into the flask, stirred at 75° C. for 2 hours, and a solution of 0.72 g of V-601 and 36.0 g of isopropanol was further added, and the contents of the flask were stirred at 75° C. for 2 hours. Then, the temperature inside the flask was increased to 85° C., and stirring was continued for another 2 hours. As a result, a resin solution of a copolymer of phenoxyethyl acrylate/methyl methacrylate/acrylic acid (=50/45/5 [mass ratio]) was obtained.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US08752949B2
출처 데이터셋uspto-grants-2014_06
ORD IDord-351e27e72b9a4b18a78260fc637389bd
출처 메모uspto-grants-2014_06