Sodium Cyanide → HCID 12116615, 화합물

HRID 411633

반응식

HRID 411633 반응식
[CH3:1][C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][C:9]=1[O:10][CH3:11])[CH:5]=[O:6].[S:12]([CH2:22][N+:23]#[C-:24])([C:15]1[CH:21]=[CH:20][C:18]([CH3:19])=[CH:17][CH:16]=1)(=[O:14])=[O:13].[C-]#N.[Na+]>>[CH3:11][O:10][C:9]1[CH:8]=[CH:7][C:4]([C@H:5]2[O:6][CH:24]=[N:23][C@@H:22]2[S:12]([C:15]2[CH:21]=[CH:20][C:18]([CH3:19])=[CH:17][CH:16]=2)(=[O:14])=[O:13])=[CH:3][C:2]=1[CH3:1]

참가 물질

4

반응물 3

HCID 8929Sodium CyanideHCID 1229363-Methyl-4-anisaldehydeHCID 161915Tosylmethyl isocyanide

생성물 1

HCID 12116615HCID 12116615, 화합물

실험 절차

In a manner analogous to Preparation 1, 3-methyl-p-anisaldehyde (0.73 mL, 5.25 mmol), tosylmethylisocyanide (0.98 g, 5.00 mmol) and NaCN (24.5 mg, 0.50 mmol) gave the desired compound as a tan solid. MS(ES+) m/z 346.7 (M+H+).

출처 및 근거

ORD 기록
ord-feb727ce94074a1ea9c3649ed903b350
출처 데이터셋
uspto-grants-2003_05
특허 번호
US06559172B1

연결된 노트

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