참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Decanoic Acid | HCID 2969 | — |
| 반응물 | Dichloromethane | HCID 6344 | — |
| 반응물 | Sodium Bicarbonate | HCID 516892 | — |
| 반응물 | Chloromethyl chlorosulfate | HCID 2733556 | — |
| 촉매 | Tetrabutylammonium hydrogen sulfate | HCID 94433 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Chloromethyl decanoate | HCID 572571 | 100% |
반응 단계
Decanoic acid (0.2 gm, 1.2 mmol) was treated with 4 eq NaHCO3, 0.1 eq Bu4NHSO4 and, 1.2 eq ClCH2OSO2Cl in 1:1 CH2Cl2:H2O. The reaction was stirred vigorously at 0° C. for 30 min then room temperature (“RT”) for 3 hrs. Aqueous workup yielded chloromethyldecanoate (yield 100%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06559164B1 |
|---|
| 출처 데이터셋 | uspto-grants-2003_05 |
|---|
| ORD ID | ord-01ffc514e7334937b06f28c9c7eef12f |
|---|
| 출처 메모 | uspto-grants-2003_05 |
|---|
