반응식
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]23[CH2:17][CH:12]4[CH2:13][CH:14]([CH2:16][CH:10]([CH2:11]4)[CH2:9]2)[CH2:15]3)=[CH:4][C:3]=1[C:18]1[CH:23]=[C:22]([C:24]23[CH2:33][CH:28]4[CH2:29][CH:30]([CH2:32][CH:26]([CH2:27]4)[CH2:25]2)[CH2:31]3)[CH:21]=[CH:20][C:19]=1[CH3:34].C[C:36]1[CH:41]=[CH:40][C:39]([C:42]23CC4CC(CC(Br)(C4)[CH2:43]2)C3)=[CH:38][C:37]=1[C:53]1C=C(C23CC4CC(CC(Br)(C4)C2)C3)C=C[C:54]=1C>>[CH3:34][C:19]1[CH:20]=[CH:21][C:22]([C:24]23[CH2:25][CH:26]4[CH2:27][CH:28]([CH2:29][C:30]([C:7]5[CH:6]=[C:5]([C:8]#[CH:9])[CH:4]=[C:3]([C:18]#[CH:19])[CH:2]=5)([CH2:32]4)[CH2:31]2)[CH2:33]3)=[CH:23][C:18]=1[C:3]1[CH:4]=[C:5]([C:8]23[CH2:9][CH:10]4[CH2:16][CH:14]([CH2:13][C:12]([C:41]5[CH:40]=[C:39]([C:42]#[CH:43])[CH:38]=[C:37]([C:53]#[CH:54])[CH:36]=5)([CH2:11]4)[CH2:17]2)[CH2:15]3)[CH:6]=[CH:7][C:2]=1[CH3:1]참가 물질
3
실험 절차
From the obtained 2,2′-dimethyl-5,5′-bis(1-adamantyl)-biphenyl 10 g, the same method as in Synthesis Example 7 was used to synthesize 2,2′-dimethyl-5,5′-bis(3-bromo-1-adamantyl)biphenyl 4.5 g, then the same method as in Synthesis Example 3 was used to obtain 2,2′-dimethyl-5,5′-bis(3-(3,5-diethynylphenyl)-1-adamantyl)biphenyl 3.8 g.
후처리
- customthe same method as in Synthesis Example 3
출처 및 근거
- ORD 기록
- ord-8af8d5cfae954018b9b767f588c5e2c4
- 출처 데이터셋
- uspto-grants-2013_09
- 특허 번호
- US08530596B2
연결된 노트
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