2-Nitro-4-(trifluoromethanesulfonyl)aniline → 4-(Trifluoromethanesulfonyl)benzene-1,2-diamine
반응식
[N+:1]([C:4]1[CH:9]=[C:8]([S:10]([C:13]([F:16])([F:15])[F:14])(=[O:12])=[O:11])[CH:7]=[CH:6][C:5]=1[NH2:17])([O-])=O>CCO.[Pd]>[F:15][C:13]([F:14])([F:16])[S:10]([C:8]1[CH:9]=[C:4]([NH2:1])[C:5]([NH2:17])=[CH:6][CH:7]=1)(=[O:11])=[O:12]참가 물질
4
실험 절차
Dissolve 2-nitro-4-trifluoromethylsulfonyl-phenylamine (530 mg) in EtOH (50 mL) and hydrogenate over Pd/C (10%) for 6 hours. Filter the mixture and concentrate the filtrate in vacuo to obtain 4-trifluoromethylsulfonyl-benzene-1,2-diamine.
후처리
- filtrationFilter the mixture
- concentrationconcentrate the filtrate in vacuo
출처 및 근거
- ORD 기록
- ord-5ebcd2b36f9149319472542168f59a23
- 출처 데이터셋
- uspto-grants-2003_05
- 특허 번호
- US06566367B2
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