Chlorine monoxide → 2-(1-Chloroethyl)benzenesulfonyl chloride
반응식
[CH2:1]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[S:9]([Cl:12])(=[O:11])=[O:10])[CH3:2].O(Cl)[Cl:14]>C(Cl)(Cl)(Cl)Cl>[Cl:14][CH:1]([C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[S:9]([Cl:12])(=[O:11])=[O:10])[CH3:2]참가 물질
4
실험 절차
A solution of 2-ethylbenzenesulfonyl chloride (obtained by chlorosulfonation of ethylbenzene) (7.78 g) in carbon tetrachloride (5.0 ml) was contacted with a solution of dichlorine monoxide (82 mmol) in carbon tetrachloride (100 ml) and the mixture was heated in a closed system at 50°-60° for 16 hrs. The mixture was dried (MgSO4) and volatiles were removed under vacuum. The residue was kugelrohr distilled to give 7.63 g of colorless oil, bp 75°-80° (0.15 mm). 1H nmr δCDCl3TMS 8.20-7.35 (m). 6.13 (q, J=7 Hz), 1.90 (d, J=7 Hz).
후처리
- temperaturethe mixture was heated in a closed system at 50°-60° for 16 hrs
- dry with materialThe mixture was dried (MgSO4) and volatiles
- customwere removed under vacuum
- distillationThe residue was kugelrohr distilled
출처 및 근거
- ORD 기록
- ord-5a26a82ee29e4183bd849568dc3c6a8f
- 출처 데이터셋
- uspto-grants-1988_02
- 특허 번호
- US04723990
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