참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Dichloromethane | HCID 6344 | — |
| 반응물 | Methyl vinyl ketone | HCID 6570 | — |
| 반응물 | Chloroprene | HCID 31369 | — |
| 반응물 | Aluminum(III) Chloride | HCID 6451240 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 1-Chloro-4-acetyl-cyclohexene | HCID 14365660 | — |
반응 단계
To a solution of 98.1 parts of methyl vinyl ketone, 187 parts of anhydrous aluminum chloride and 1980 parts of methylene chloride was added 123 parts of chloroprene and the mixture was stirred at 25° C. for three hours and left standing for another 16 hours. Water was added to the reaction mixture and the organic layer was washed with 5% hydrochloric acid. Distillation gave a center cut of 61 parts of 1-chloro-4-acetyl-cyclohexene (125°-6° C./20 mm Hg). Reference: A. A. Petrov and N. P. Sopov, CA 42, 1910h (1948).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04792618 |
|---|
| 출처 데이터셋 | uspto-grants-1988_12 |
|---|
| ORD ID | ord-19e3802694574392bda66521ea4de726 |
|---|
| 출처 메모 | uspto-grants-1988_12 |
|---|
