Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3-Chloro-2-methyl-1-propene → 4-Methyl-7-methallyloxy-1-indanone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3-Chloro-2-methyl-1-propene | HCID 11241 | — |
| 반응물 | Potassium Hydroxide | HCID 14797 | — |
| 반응물 | 7-Hydroxy-4-methyl-1-indanone | HCID 12436244 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | 4-Methyl-7-methallyloxy-1-indanone | HCID 13604151 | — |
반응 단계
Into a solution of 15 g of 4-methyl-7-hydroxy-1-indanone and 7.95 g of potassium hydroxide in 200 ml of methanol was added 13.55 ml of methallyl chloride, and the mixture was refluxed by heating for 11 hours. The insoluble matters in the reaction mixture were removed by filtration, then the solvent was removed by evaporation. The residue obtained was purified by means of a silica gel column chromatography (eluent: n-hexane: dichloromethane=1:1) to obtain 9 g of 4-methyl-7-methallyloxy-1-indanone.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04792628 |
| 출처 데이터셋 | uspto-grants-1988_12 |
| ORD ID | ord-cd8b7b060be64f7289e4470cda2668f0 |
| 출처 메모 | uspto-grants-1988_12 |