Nickel(II) bromide ethylene glycol dimethyl ether complex → HCID 86651358, 화합물

HRID 416205노트

반응식

HRID 416205 반응식
[Ni:1]([Br:3])[Br:2].COCCOC.[CH3:10][Si:11]([CH3:29])([CH3:28])[C:12]1[CH:13]=[CH:14][C:15]([C:18]2[CH:23]=[CH:22][C:21]([Si:24]([CH3:27])([CH3:26])[CH3:25])=[CH:20][N:19]=2)=[N:16][CH:17]=1>C(O)C>[Ni:1]([Br:3])[Br:2].[CH3:25][Si:24]([CH3:27])([CH3:26])[C:21]1[CH:22]=[CH:23][C:18]([C:15]2[CH:14]=[CH:13][C:12]([Si:11]([CH3:29])([CH3:28])[CH3:10])=[CH:17][N:16]=2)=[N:19][CH:20]=1

참가 물질

4

반응물 2

HCID 6098672Nickel(II) bromide ethylene glycol dimethyl ether complexHCID 12984525HCID 12984525, 화합물

생성물 1

HCID 86651358HCID 86651358, 화합물수율 42.3%

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

To a glass reaction container equipped with a cooling apparatus, 2.5 g of nickel bromide•ethylene glycol dimethyl ether, 2.56 g of 5,5′-bis(trimethylsilyl)-2,2′-bipyridine and 14 mL of ethanol were added at room temperature under a nitrogen atmosphere. The obtained mixture was reacted at 65° C. for 2 hours to obtain a crude product. The obtained crude product was recrystallized using hexane and ethanol to obtain 1.78 g of 5,5′-bis(trimethylsilyl)-2,2′-bipyridine nickel dibromide.

후처리

  1. customTo a glass reaction container
  2. additionwere added at room temperature under a nitrogen atmosphere
  3. customThe obtained mixture was reacted at 65° C. for 2 hours
  4. customto obtain a crude product
  5. customThe obtained crude product
  6. customwas recrystallized

출처 및 근거

ORD 기록
ord-4b084f58c9a94dfd91cf4c2311e17d6f
출처 데이터셋
uspto-grants-2012_01
특허 번호
US08088883B2

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