Monoethyl malonate → HCID 178450104, 화합물
반응식
[NH:1]1[C:5]2[CH:6]=[CH:7][C:8]([NH2:10])=[CH:9][C:4]=2[N:3]=[CH:2]1.[CH2:11]([O:15][C:16]1[CH:23]=[CH:22][C:19]([CH:20]=O)=[CH:18][CH:17]=1)[CH2:12][CH2:13][CH3:14].C([O:26][C:27]([CH2:29][C:30](O)=[O:31])=O)C.C(=O)(OC)OC(C)(C)C[N+]#[C-].CC(C)([O-])C.[Na+]>>[NH:1]1[C:5]2[CH:6]=[CH:7][C:8]([N:10]3[CH:20]([C:19]4[CH:22]=[CH:23][C:16]([O:15][CH2:11][CH2:12][CH2:13][CH3:14])=[CH:17][CH:18]=4)[C:27](=[O:26])[CH2:29][C:30]3=[O:31])=[CH:9][C:4]=2[N:3]=[CH:2]1참가 물질
6
실험 절차
The compound was synthesized starting from 1H-benzo[d]imidazol-5-amine (0.798 g, 6 mmol), 4-butoxybenzaldehyde (1.0 g, 6 mmol), 2-(ethoxycarbonyl)acetic acid (0.79 g, 6 mmol), 1-isocyano-2-methylpropan-2-yl methyl carbonate (0.943 g, 6 mmol) and sodium tert.-butoxide (0.572 g, 5 mmol) according to method 3.