Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
4'-Methoxyacetophenone → (E)-1-(4-methoxyphenyl)-N-[(4-nitrophenyl)methoxy]ethanimine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 4'-Methoxyacetophenone | HCID 7476 | — |
| 반응물 | Hydroxylamine, O-((4-nitrophenyl)methyl)-, hydrochloride (1:1) | HCID 74967 | — |
| 생성물 | (E)-1-(4-methoxyphenyl)-N-[(4-nitrophenyl)methoxy]ethanimine | HCID 25100093 | 68% |
반응 단계
4′-Methoxyacetophenone (21) (150 mg, 1.00 mmol) was condensed with compound 19 (225 mg, 1.10 mmol) according to the general procedure II-A defined above. After heating the reaction mixture for 2 h it was cooled and the resulting solid filtered off and washed with cold isopropanol (3.0 mL) to afford the title compound CP30253 (204 mg, 68%) as a pale-yellow solid, m.p. 88.2-89.5° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08536157B2 |
| 출처 데이터셋 | uspto-grants-2013_09 |
| ORD ID | ord-4b207b98aed64036ba86b4d7c46916a6 |
| 출처 메모 | uspto-grants-2013_09 |