홈MCP워크벤치Skills
홈워크벤치알림마이페이지
llms.txt · MCP 가이드개인정보처리방침 · 이용약관 · 지원v1.8.0
  1. 홈
  2. /반응

Pyridine → (E)-5,6-dimethoxy-N-[(4-nitrophenyl)methoxy]-2,3-dihydroinden-1-imine

HRID 41947
노트
인쇄 미리보기

반응식

HRID 41947 반응식
COC1C=C2C(=CC=1OC)C(=O)CC2.Cl.[N+](C1C=CC(CNO)=CC=1)([O-])=O.N1C=CC=CC=1.[N+:34]([C:37]1[CH:59]=[CH:58][C:40]([CH2:41][O:42]/[N:43]=[C:44]2\[CH2:45]C[CH2:47][C:48]3[C:53]\2=[CH:52][C:51]([O:54][CH3:55])=[C:50]([O:56][CH3:57])[CH:49]=3)=[CH:39][CH:38]=1)([O-:36])=[O:35]>C(O)C.C(OCC)(=O)C.CCCCCC>[N+:34]([C:37]1[CH:59]=[CH:58][C:40]([CH2:41][O:42]/[N:43]=[C:44]2\[CH2:45][CH2:47][C:48]3[C:53]\2=[CH:52][C:51]([O:54][CH3:55])=[C:50]([O:56][CH3:57])[CH:49]=3)=[CH:39][CH:38]=1)([O-:36])=[O:35]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

7

반응물 4

HCID 1049PyridineHCID 750185,6-Dimethoxy-1-indanoneHCID 86662371(4-Nitrobenzyl)hydroxylamine hydrochlorideHCID 87138450(E)-6,7-dimethoxy-N-[(4-nitrophenyl)methoxy]-3,4-dihydro-2H-naphthalen-1-imine

생성물 1

HCID 87138614(E)-5,6-dimethoxy-N-[(4-nitrophenyl)methoxy]-2,3-dihydroinden-1-imine수율 53%

시약·촉매·용매 2

HCID 702Ethanol용매HCID 21226206Ethyl acetate hexane용매

실험 절차

5,6-Dimethoxy-1-indanone (104 mg, 0.54 mmol) was subjected to reaction with (4-nitrobenzyl)hydroxylamine hydrochloride (125 mg, 0.61 mmol) in ethanol (5 mL) and pyridine (0.7 mL, 9.03 mmol) under the same conditions as described for (E)-6,7-dimethoxy-3,4-dihydronaphthalen-1(2H)-one O-4-nitrobenzyl oxime. Subjection of the material obtained on work up to flash chromatography (3:7 v/v ethyl acetate/hexane elution) afforded a ca. 3:1 mixture of the E- and Z-isomeric forms of the title compound (98 mg, 53%) as a pale-yellow crystalline solid, m.p. 139-144° C., Rf 0.3.

후처리

  1. customafforded

출처 및 근거

ORD 기록
ord-c9949940468a48e7a9d9394619648779
출처 데이터셋
uspto-grants-2013_09
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US08536157B2

반응 노트

불러오는 중…

이 페이지에서참가 물질실험 절차후처리출처 및 근거반응 노트