Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethanol → HCID 87138499, 화합물
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethanol | HCID 702 | — |
| 반응물 | Pyridine | HCID 1049 | — |
| 반응물 | 7-Hydroxy-6-methoxy-1-tetralone | HCID 316840 | — |
| 반응물 | (4-Nitrobenzyl)hydroxylamine hydrochloride | HCID 86662371 | — |
| 생성물 | HCID 87138499 | HCID 87138499 | 55% |
반응 단계
7-Hydroxy-6-methoxy-1-tetralone (105 mg, 0.55 mmol) was subjected to reaction with (4-nitrobenzyl)hydroxylamine hydrochloride (122 mg, 0.60 mmol) in ethanol (5 mL) and pyridine (0.5 mL, 6.45 mmol) under the same conditions as described for (E)-6,7-dimethoxy-3,4-dihydronaphthalen-1(2R)-one O-4-nitrobenzyl oxime. The solid obtained on work up was recrystallised (isopropanol) to yield the title compound (103 mg, 55%) as off-white crystals, m.p. 125-127° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08536157B2 |
| 출처 데이터셋 | uspto-grants-2013_09 |
| ORD ID | ord-972e713bd1f74c03bd12922506f473ce |
| 출처 메모 | uspto-grants-2013_09 |