(+)-tert-Butyl glycidyl ether → HCID 66676935, 화합물
반응식
C([O:5][C:6](=O)[NH:7][CH2:8][CH2:9][O:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=1[O:17][CH3:18])C(C)C.C[C:21]([CH3:24])([O-:23])[CH3:22].[Li+].C([O:30]C[C@@H]1CO1)(C)(C)C>CN(C)C=O>[CH3:18][O:17][C:12]1[CH:13]=[CH:14][CH:15]=[CH:16][C:11]=1[O:10][CH2:9][CH2:8][N:7]1[CH2:22][C@@H:21]([CH2:24][OH:30])[O:23][C:6]1=[O:5]참가 물질
5
실험 절차
Using N,N-dimethylformamide solution of isobutyl-2-(2-methoxyphenoxy)ethylcarbamate 26.7 g (0.1 mol), lithium-t-butoxide 1.60 g (0.02 mol) and (S)-2-t-butoxymethyl-oxiran 14.3 g (0.11 mol), the procedures as described in Example 1 were carried out to obtain the targeted product.
후처리
- customto obtain the targeted product
출처 및 근거
- ORD 기록
- ord-58c57d3cdd4c43489cc87d9d16042802
- 출처 데이터셋
- uspto-grants-2012_01
- 특허 번호
- US08101781B2
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