Oxalyl chloride → 2-Furansulfonyl isocyanate

HRID 426449

반응식

HRID 426449 반응식
C(Cl)(=O)[C:2](Cl)=[O:3].N12CCC(CC1)CN2.[O:15]1[CH:19]=[CH:18][CH:17]=[C:16]1[S:20]([NH2:23])(=[O:22])=[O:21]>C1(C)C=CC=CC=1>[O:15]1[CH:19]=[CH:18][CH:17]=[C:16]1[S:20]([N:23]=[C:2]=[O:3])(=[O:22])=[O:21]

참가 물질

5

반응물 3

HCID 65578Oxalyl chlorideHCID 136165Diazabicyclo(2.2.2)octaneHCID 13668256Furan-2-sulfonamide

생성물 1

HCID 233424782-Furansulfonyl isocyanate

시약·촉매·용매 1

HCID 1140Toluene용매

실험 절차

Dry toluene (150 ml), 25 ml oxalyl chloride (295), and a trace of DABCO (diaza-bicyclo[2.2.2]octane) were heated to 90°. Ten g of 2-furansulfonamide was added over a 15 minute period and the mixture was held at 95° for 2 hours. After filtering, the solvent was removed under vacuum to yield 2.1 g of an oil showing the characteristic isocyanate absorption in the infrared (2280 cm-1).

후처리

  1. filtrationAfter filtering
  2. customthe solvent was removed under vacuum

출처 및 근거

ORD 기록
ord-e461e0af470f4738aede9d41910ec5f4
출처 데이터셋
uspto-grants-1979_10
특허 번호
US04169719

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