HCID 20389413, 화합물 → 1-Methyl-3,5-dinitro-2-phenoxybenzene

HRID 426670

반응식

HRID 426670 반응식
[N+:1]([C:4]1[C:5](Br)=[C:6]([CH3:13])[CH:7]=[C:8]([N+:10]([O-:12])=[O:11])[CH:9]=1)([O-:3])=[O:2].[C:15]1([O-:21])[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[K+]>CN(C)C=O>[N+:1]([C:4]1[C:5]([O:21][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[C:6]([CH3:13])[CH:7]=[C:8]([N+:10]([O-:12])=[O:11])[CH:9]=1)([O-:3])=[O:2]

참가 물질

4

반응물 2

HCID 20389413HCID 20389413, 화합물HCID 23670670Potassium phenoxide

생성물 1

HCID 157068691-Methyl-3,5-dinitro-2-phenoxybenzene수율 17.7%

시약·촉매·용매 1

HCID 6228Dimethylformamide용매

실험 절차

A mixture of 6 gm of 3,5-dinitro-2-bromotoluene and 3 gm of potassium phenolate in 20 ml of dimethyl formamide was boiled under reflux for 20 hours. Subsequently, the solution was poured on 200 gm of ice and the precipitate was filtered off. After recrystallization from ethanol, there was obtained 1.1 gm of yellow crystals with a melting point of 103° C. The mass spectrum showed a molecular mass of 274 (calculated 274).

후처리

  1. temperatureunder reflux for 20 hours
  2. filtrationthe precipitate was filtered off
  3. customAfter recrystallization from ethanol

출처 및 근거

ORD 기록
ord-2c575f98fe3c4c65956e3e8b12047ab5
출처 데이터셋
uspto-grants-1979_10
특허 번호
US04171203

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