1-Naphthyl acetate → 1-Naphthol

HRID 426882

반응식

HRID 426882 반응식
[C:1]([O:4][C:5]1[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[CH:8]=[CH:7][CH:6]=1)(=[O:3])[CH3:2]>O>[C:5]1([OH:4])[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[CH:8]=[CH:7][CH:6]=1.[C:1]([O:4][C:5]1[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[CH:8]=[CH:7][CH:6]=1)(=[O:3])[CH3:2]

참가 물질

4

반응물 1

HCID 132471-Naphthyl acetate

생성물 2

HCID 70051-Naphthol수율 86.5%HCID 132471-Naphthyl acetate

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
200 °C

실험 절차

201 parts of α-naphthyl acetate and 45 parts of water are introduced into a stirred autoclave, the mixture is heated to 200° C., whilst stirring, resulting in an autogenous pressure of 15 bars. After 75 minutes at 200° C., the emulsion formed changes to a clear solution. After 6 hours at 200° C., the mixture is distilled. 134.5 parts of α-naphthol (86.5% of theory) of boiling point 130° C./13 mbar, 3 parts of naphthyl acetate and 9.5 parts of residue are obtained.

후처리

  1. customresulting in an autogenous pressure of 15 bars
  2. customthe emulsion formed changes to a clear solution
  3. waitAfter 6 hours at 200° C.
  4. distillationthe mixture is distilled

출처 및 근거

ORD 기록
ord-49cc8431cb854a72995895c0ee430d45
출처 데이터셋
uspto-grants-1979_10
특허 번호
US04171459

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