Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetonitrile → 3-(4-(Acryloyloxy)butoxy)-2-hydroxypropyl 2-benzoylbenzoate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetonitrile | HCID 6342 | — |
| 반응물 | 2-Benzoylbenzoic Acid | HCID 6813 | — |
| 반응물 | 2,6-Di-tert-butyl-4-methylphenol | HCID 31404 | — |
| 반응물 | 4-Hydroxybutylacrylate glycidylether | HCID 22323150 | — |
| 촉매 | Tetrabutylammonium Bromide | HCID 74236 | — |
| 용매 | Dimethylacetamide | HCID 31374 | — |
| 생성물 | 3-(4-(Acryloyloxy)butoxy)-2-hydroxypropyl 2-benzoylbenzoate | HCID 58325511 | — |
반응 단계
A reaction mixture containing 2-benzoyl benzoic acid (40.0 g, 0.1722 mol), acetonitrile (300 mL), dimethylacetamide (10 mL), tetrabutylammonium bromide (5.6 g, 17.22 mmol) and 2,6-di-tert-butyl-4-methylphenol (0.3 g, 1.4 mmol) was heated to reflux. At this temperature 4-hydroxybutylacrylate glycidylether (28.0 g, 140 mmol) was added and the mixture was allowed to stir at reflux temperature for 16 hours.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08536217B2 |
| 출처 데이터셋 | uspto-grants-2013_09 |
| ORD ID | ord-320c13860a99488e881a36e355cfd6ef |
| 출처 메모 | uspto-grants-2013_09 |