반응식
[CH3:1][C:2]1([CH3:25])[CH2:11][CH2:10][C:9]([CH3:13])([CH3:12])[C:8]2[CH:7]=[C:6]([C:14]3[CH:24]=[CH:23][CH:22]=[CH:21][C:15]=3[C:16](OCC)=[O:17])[CH:5]=[CH:4][C:3]1=2.[H-].C([Al+]CC(C)C)C(C)C>>[CH3:1][C:2]1([CH3:25])[CH2:11][CH2:10][C:9]([CH3:12])([CH3:13])[C:8]2[CH:7]=[C:6]([C:14]3[CH:24]=[CH:23][CH:22]=[CH:21][C:15]=3[CH2:16][OH:17])[CH:5]=[CH:4][C:3]1=2참가 물질
3
실험 절차
Employing the same general procedure as used for the preparation of 3-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphth-2-yl)but-2(Z)-en-1-ol (Compound C), but instead using 420 mgs (1.25 mmols) ethyl 2-[5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphth-2yl]benzoate (Compound H) and 6 mmols of diisobutylaluminiumhydride the title compound was obtained as a white solid.
출처 및 근거
- ORD 기록
- ord-4b95b2c90ddd4295b3b5c3a4d713da34
- 출처 데이터셋
- uspto-grants-2001_11
- 특허 번호
- US06313163B1
연결된 노트
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