참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | N-methyl-2-pyrrolidone | HCID 13387 | — |
| 반응물 | Diallylamine | HCID 31279 | — |
| 반응물 | 3-Fluoro-4-nitroaniline | HCID 75401 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | N,N-diallyl-6-nitro-1,3-benzenediamine | HCID 22251449 | 98.6% |
반응 단계
A mixture of 3-fluoro-4-nitroaniline (1.56 g, 10 mmol), 1-methylpyrolidinone (10 mL), diallylamine (1.94 g, 20 mmol) and potassium carbonate (1.38 g, 10 mmol) was heated to 115-125 ° C. for 9.5 h. The mixture was diluted with water, and extracted with ethyl ether. The combined extracts were washed with water, washed with saturated brine solution, and dried over magnesium sulfate. The extract was concentrated to give N,N-diallyl-6-nitro-1,3-benzenediamine as an orange oil (2.3 g).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06313348B1 |
|---|
| 출처 데이터셋 | uspto-grants-2001_11 |
|---|
| ORD ID | ord-28b93eaa005f48068dd8c1543a6e8d6e |
|---|
| 출처 메모 | uspto-grants-2001_11 |
|---|
