Diisobutylaluminumhydride → 2-Chloro-4,5-bis-[(2-methoxyethoxy)-methoxy]-styrol

HRID 428840노트

반응식

HRID 428840 반응식
[Cl:1][C:2]1[CH:12]=[C:11]([O:13][CH2:14][O:15][CH2:16][CH2:17][O:18][CH3:19])[C:10]([O:20][CH2:21][O:22][CH2:23][CH2:24][O:25][CH3:26])=[CH:9][C:3]=1[CH:4]=[CH:5]C([O-])=O.[H-].C([Al+]CC(C)C)C(C)C>CCCCCC>[Cl:1][C:2]1[CH:12]=[C:11]([O:13][CH2:14][O:15][CH2:16][CH2:17][O:18][CH3:19])[C:10]([O:20][CH2:21][O:22][CH2:23][CH2:24][O:25][CH3:26])=[CH:9][C:3]=1[CH:4]=[CH2:5]

참가 물질

4

반응물 2

HCID 21225700DiisobutylaluminumhydrideHCID 734318772-Chloro-4,5-bis-[(2-methoxyethoxy)-methoxy]-styryl-carboxylate

생성물 1

HCID 183591822-Chloro-4,5-bis-[(2-methoxyethoxy)-methoxy]-styrol수율 34.2%

시약·촉매·용매 1

HCID 8058Hexane용매

실험 절차

Using the procedure of Stage C of Example 40, 60.8 g of the ester of Stage C and 293 ml of a molar solution of diisobutyl-aluminum hydride in hexane were reacted to obtain 18.5 g of the expected product.

후처리

  1. customwere reacted

출처 및 근거

ORD 기록
ord-a4556e844f0b479d9d19fa9289fefd1c
출처 데이터셋
uspto-grants-2001_11
특허 번호
US06313305B1

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