4-Methylphthalic anhydride → 2-Hydroxy-5-methyl-1H-isoindole-1,3(2H)-dione
반응식
[CH3:1][C:2]1[CH:3]=[C:4]2[C:9](=O)[O:8][C:6](=[O:7])[C:5]2=[CH:11][CH:12]=1.P([O-])([O-])([O-])=O.[OH:18][NH3+:19].O[NH3+].O[NH3+]>O>[CH3:1][C:2]1[CH:3]=[C:4]2[C:9](=[O:8])[N:19]([OH:18])[C:6](=[O:7])[C:5]2=[CH:11][CH:12]=1참가 물질
4
실험 절차
500 mg (3.08 mmol) of 4-methylphthalic anhydride and 243 mg (1.23 mmol) of hydroxylammonium phosphate were mixed and heated with 1 ml of water at a bath temperature of 130° C. for 3 hours. The cooled mixture was digested with 30 ml of water. The precipitate which formed was filtered off with suction and dried at 60° C. under reduced pressure. The yield was 437 mg (80%).
후처리
- customThe precipitate which formed
- filtrationwas filtered off with suction
- customdried at 60° C. under reduced pressure
출처 및 근거
- ORD 기록
- ord-29ef0dfb09044e35ad079fdeef631d48
- 출처 데이터셋
- uspto-grants-2001_11
- 특허 번호
- US06316639B1
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