참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Styrene | HCID 7501 | — |
| 반응물 | Chlorobenzene | HCID 7964 | — |
| 생성물 | 1,1-Diphenylethylene | HCID 10740 | 12.4% |
| 생성물 | trans-Stilbene | HCID 638088 | 86.7% |
| 생성물 | cis-Stilbene | HCID 5356785 | 0.9% |
반응 단계
A reaction is performed as described in Example 1, except that 102.8 mg (0.99 mmol) of styrene and 164.8 mg (1.46 mmol) of chlorobenzene are used, and the reaction mixture is stirred at 150° C. for 5.5 hours. With 94.6% conversion of Cl-benzene, an 82.1% yield of Heck products (86.7% trans-stilbene, 0.9% cis-stilbene, 12.4% 1,1-diphenylethene) is obtained.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US06316675B1 |
|---|
| 출처 데이터셋 | uspto-grants-2001_11 |
|---|
| ORD ID | ord-0f3dd49aeb5e4d00b6d810eb17ec34cb |
|---|
| 출처 메모 | uspto-grants-2001_11 |
|---|
