참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Myrcene | HCID 31253 | — |
| 반응물 | Vinyl pivalate | HCID 256591 | — |
| 용매 | Methanol | HCID 887 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 4-Vinyl-8-methyl-1,7-nonadienyl pivalate | HCID 54417067 | — |
반응 단계
23.7 mg (0.055 mmol) of (N-2-aminomethyl-p-toluenesulfonamide)(η6-benzene)ruthenium (II) chloride obtained in the Reference Example 4 and 17.5 mg (0.068 mmol) of silver triflate were mixed in 2 ml of methanol, to which were added 2 ml (purity: 78%, 1.25 g, 9.2 mmol) of myrcene and 1.73 g (13 mmol) of vinyl pivalate. The mixture was stirred at 70° C. for 6 hours. The reaction mixture was diluted with water and the organic layer was analyzed by gas chromatography to confirm that the title compound (addition product) having a purity of 76% (regioisomer: 26%) was produced at a conversion rate of 17%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US06323174B1 |
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| 출처 데이터셋 | uspto-grants-2001_11 |
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| ORD ID | ord-fa839a17096b46da97b5908456ddc612 |
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| 출처 메모 | uspto-grants-2001_11 |
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