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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 430452생성일: 2026년 10월 25일

Myrcene → 4-Vinyl-8-methyl-1,7-nonadienyl pivalate

https://huagongshe.com/reaction/430452

반응식

참여 물질

역할이름HCID투입량
반응물MyrceneHCID 31253—
반응물Vinyl pivalateHCID 256591—
용매MethanolHCID 887—
용매WaterHCID 962—
생성물4-Vinyl-8-methyl-1,7-nonadienyl pivalateHCID 54417067—

반응 조건

온도70 °C

반응 단계

23.7 mg (0.055 mmol) of (N-2-aminomethyl-p-toluenesulfonamide)(η6-benzene)ruthenium (II) chloride obtained in the Reference Example 4 and 17.5 mg (0.068 mmol) of silver triflate were mixed in 2 ml of methanol, to which were added 2 ml (purity: 78%, 1.25 g, 9.2 mmol) of myrcene and 1.73 g (13 mmol) of vinyl pivalate. The mixture was stirred at 70° C. for 6 hours. The reaction mixture was diluted with water and the organic layer was analyzed by gas chromatography to confirm that the title compound (addition product) having a purity of 76% (regioisomer: 26%) was produced at a conversion rate of 17%.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US06323174B1
출처 데이터셋uspto-grants-2001_11
ORD IDord-fa839a17096b46da97b5908456ddc612
출처 메모uspto-grants-2001_11