Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzene, 1-chloro-4-ethynyl- → Z-4-chlorostyryl 2-chlorobenzylsulfide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzene, 1-chloro-4-ethynyl- | HCID 70118 | — |
| 반응물 | 2-Chlorobenzyl mercaptan | HCID 580759 | — |
| 반응물 | Sodium | HCID 5360545 | — |
| 생성물 | Z-4-chlorostyryl 2-chlorobenzylsulfide | HCID 86588938 | — |
반응 단계
A solution of 4-chlorophenylacetylene (0.02 mol) and 2-chlorobenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to Procedure 2 to form (Z)-4-chlorostyryl 2-chlorobenzylsulfide. The title compound was obtained in 73% yield following oxidation. 1HNMR (CDC13) δ4.56 (2H, s), 6.70 (1H, d, JH,H=12.05), 7.18-7.64 (8H aromatic+1H ethylenic).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06656973B2 |
| 출처 데이터셋 | uspto-grants-2003_12 |
| ORD ID | ord-7d2388c45870420b822bfdc985adb262 |
| 출처 메모 | uspto-grants-2003_12 |