Dimethyl Sulfide → Trimethylsulfonium Triflate

HRID 43293

반응식

HRID 43293 반응식
[CH3:1][S:2][CH3:3].[CH3:4][O:5][S:6]([C:9]([F:12])([F:11])[F:10])(=[O:8])=[O:7]>ClCCl>[O-:8][S:6]([C:9]([F:12])([F:11])[F:10])(=[O:7])=[O:5].[CH3:1][S+:2]([CH3:4])[CH3:3]

참가 물질

4

반응물 2

HCID 1068Dimethyl SulfideHCID 9526Methyl triflate

생성물 1

HCID 10933171Trimethylsulfonium Triflate

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

16 mmol of dimethyl sulfide was dissolved in 10 ml of dichloromethane at 0° C., and about 17 mmol of methyltrifluoromethane sulfonate was slowly dripped to the mixture to obtain a white solid product. The solid product was filtered and dried for 1 hour in an oven at 50° C. to obtain the following product:

후처리

  1. customto obtain a white solid product
  2. filtrationThe solid product was filtered
  3. customdried for 1 hour in an oven at 50° C.
  4. customto obtain the following product

출처 및 근거

ORD 기록
ord-5cc9413dfef7447db1b13d03a866a5a8
출처 데이터셋
uspto-grants-2013_09
특허 번호
US08536347B2

연결된 노트

불러오는 중…