p-Toluidine → 2-hydroxy-N-(4-methylphenyl)benzamide

HRID 433027

반응식

[C:1]([O:10]C1C=CC=CC=1)(=O)[C:2]1[C:3](=[CH:5][CH:6]=[CH:7][CH:8]=1)[OH:4].[NH2:17][C:18]1[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=1>>[CH3:24][C:21]1[CH:22]=[CH:23][C:18]([NH:17][C:1](=[O:10])[C:2]2[C:3](=[CH:5][CH:6]=[CH:7][CH:8]=2)[OH:4])=[CH:19][CH:20]=1

참가 물질

반응물 2

HCID 7813p-Toluidine

HCID 8361Phenyl Salicylate

생성물 1

HCID 4788052-hydroxy-N-(4-methylphenyl)benzamide

실험 절차

The 4′-methyl-salicylanilide was prepared by condensing phenyl salicylate with 4-toluidine then purified as described in Example 2a. A ligand mixture was then prepared from 4′-methyl-salicylanilide and binaphthol using the procedure described in Example 5a. 31P NMR (121.77 MHz): several peaks between 117.1-117.8 ppm.

후처리

customthen purified
customA ligand mixture was then prepared from 4′-methyl-salicylanilide and binaphthol using the procedure

출처 및 근거

ORD 기록: ord-fc21bdecdfb54a22b3196ecf9c212560
출처 데이터셋: uspto-grants-2003_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06664427B1

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