P-Anisidine → N-(4-Methoxyphenyl)-2-hydroxybenzamide

반응식

[C:1]([O:10]C1C=CC=CC=1)(=O)[C:2]1[C:3](=[CH:5][CH:6]=[CH:7][CH:8]=1)[OH:4].[NH2:17][C:18]1[CH:23]=[CH:22][C:21]([O:24][CH3:25])=[CH:20][CH:19]=1>>[CH3:25][O:24][C:21]1[CH:22]=[CH:23][C:18]([NH:17][C:1](=[O:10])[C:2]2[C:3](=[CH:5][CH:6]=[CH:7][CH:8]=2)[OH:4])=[CH:19][CH:20]=1

참가 물질

반응물 2

HCID 7732P-Anisidine

HCID 8361Phenyl Salicylate

생성물 1

HCID 478806N-(4-Methoxyphenyl)-2-hydroxybenzamide

실험 절차

The 4′-methoxy-salicylanilide was prepared by condensing phenyl salicylate with 4-aminoanisole then purified as described in Example 2a. The mixture of ligands was then prepared from 4′-methoxy-salicylanilide and 1,1′-bi-2-naphthol using the procedure described in Example 5a. 31P NMR (121.77 MHz): several peaks between 116-118 ppm.

후처리

customthen purified
additionThe mixture of ligands
customwas then prepared from 4′-methoxy-salicylanilide and 1,1′-bi-2-naphthol using the procedure

출처 및 근거

ORD 기록: ord-2fd168cee4a14c97a4b946f0e3f1930d
출처 데이터셋: uspto-grants-2003_12
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06664427B1

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