(R)-(-)-1-Methyheptyl 4-Methoxycarbonyloxybenzoate → (R)-(-)-1-Methylheptyl 4-Hydroxybenzoate

HRID 433043노트

반응식

HRID 433043 반응식
COC([O:5][C:6]1[CH:22]=[CH:21][C:9]([C:10]([O:12][C@H:13]([CH3:20])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])=[O:11])=[CH:8][CH:7]=1)=O>C(O)C.N>[OH:5][C:6]1[CH:22]=[CH:21][C:9]([C:10]([O:12][C@H:13]([CH3:20])[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])=[O:11])=[CH:8][CH:7]=1

참가 물질

4

반응물 1

HCID 70010659(R)-(-)-1-Methyheptyl 4-Methoxycarbonyloxybenzoate

생성물 1

HCID 13980124(R)-(-)-1-Methylheptyl 4-Hydroxybenzoate

시약·촉매·용매 2

HCID 222Ammonia용매HCID 702Ethanol용매

실험 절차

Compound 3 (11.6 g, 38 mmol) in ethanol (200 ml) and aqueous ammonia (50 ml) was stirred overnight. The solvents were removed in vacuo and the resulting colourless oil was purified by column chromatography (ethyl acetate) on silica.

후처리

  1. customThe solvents were removed in vacuo
  2. customthe resulting colourless oil was purified by column chromatography (ethyl acetate) on silica

출처 및 근거

ORD 기록
ord-b0f16c51de7747f9ab721b7f67c9b915
출처 데이터셋
uspto-grants-2003_12
특허 번호
US06666989B1

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