Methylisothiazolinone → bis-(2-methyl-3-isothiazolone) zinc(II)chloride

HRID 434307

반응식

HRID 434307 반응식
[Cl-:1].[Zn+2:2].[Cl-].[CH3:4][N:5]1[C:9](=[O:10])[CH:8]=[CH:7][S:6]1>C(O)C>[Cl-:1].[Zn+2:2].[CH3:4][N:5]1[C:9](=[O:10])[CH:8]=[CH:7][S:6]1.[CH3:4][N:5]1[C:9](=[O:10])[CH:8]=[CH:7][S:6]1.[Cl-:1]

참가 물질

4

반응물 2

HCID 39800MethylisothiazolinoneHCID 3007855Zincchloride

생성물 1

HCID 20493155bis-(2-methyl-3-isothiazolone) zinc(II)chloride수율 92%

시약·촉매·용매 1

HCID 702Ethanol용매2회

실험 절차

To a solution of 3.4 g (0.02 mole) of anhydrous zinc chloride in 130 ml absolute ethanol was added a solution of 2-methyl-3-isothiazolone in 20 ml of absolute ethanol. The clear solution was stirred at room temperature for 30 minutes. Concentration yielded a tan solid. The solid was triturated with ether, filtered, and dried to yield 8.4 g (92%) of bis-(2-methyl-3-isothiazolone) zinc(II)chloride, m.p. 148°-151° C.

후처리

  1. concentrationConcentration
  2. customyielded a tan solid
  3. customThe solid was triturated with ether
  4. filtrationfiltered
  5. customdried

출처 및 근거

ORD 기록
ord-eb38fd615406415ebc59fd9602767606
출처 데이터셋
uspto-grants-1983_08
특허 번호
US04396413

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