Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → 4-(Trimethylsilyl)phenol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | Trimethyl{4-[(trimethylsilyl)oxy]phenyl}silane | HCID 262890 | — |
| 촉매 | Hydrochloric Acid | HCID 313 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | 4-(Trimethylsilyl)phenol | HCID 25732 | 93.4% |
반응 단계
28.7 g p-trimethylsilylphenoxytrimethylsilane was dissolved in 9 ml 95 percent ethyl alcohol. One drop of concentrated hydrochloric acid and 4 ml water were added, and the mixture was shaked for 5 minutes. After standing for another 15 minutes, the mixture was washed two times with 30 ml water and separated. The organic phase was poured into a crystallizing dish; p-trimethylsilylphenol crystallized out as white needles. After drying overnight in vacuo, 18.7 g of product was obtained (mp 76 degrees Celsius).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04396704 |
| 출처 데이터셋 | uspto-grants-1983_08 |
| ORD ID | ord-45792f8230c445798738aae519ee22a8 |
| 출처 메모 | uspto-grants-1983_08 |