Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ammonia → N-trimethylsilyl-4-nitrobenzamide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ammonia | HCID 222 | — |
| 반응물 | 4-Nitrobenzamide | HCID 12091 | — |
| 반응물 | Hexamethyldisilazane | HCID 13838 | — |
| 반응물 | Naphthalimide | HCID 66491 | — |
| 용매 | Butyl Acetate | HCID 31272 | — |
| 생성물 | N-trimethylsilyl-4-nitrobenzamide | HCID 12726300 | — |
반응 단계
4.5 ml of hexamethyldisilazane (22 mmoles) were added to a refluxing mixture of 5.0 g (30.1 mmoles) of 4-nitrobenzamide, 100 mg (0.5 mmole) of 1.8-naphthalimide and 20 ml of butyl acetate and the calculated amount of ammonia was evolved after refluxing for 35 minutes. The same experiment without catalyst was carried out and only 16% of the theoretical amount of ammonia was evolved after refluxing for 15 minutes. After refluxing for 1 hour, 83% of that amount of evolved.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04400509 |
| 출처 데이터셋 | uspto-grants-1983_08 |
| ORD ID | ord-f9c9ab949fa740f8b6236a8a66d7f676 |
| 출처 메모 | uspto-grants-1983_08 |