Sodium Azide → p-Azidomethylphenyltrimethoxysilane

반응식

Cl[CH2:2][C:3]1[CH:8]=[CH:7][C:6]([Si:9]([O:14][CH3:15])([O:12][CH3:13])[O:10][CH3:11])=[CH:5][CH:4]=1.[N-:16]=[N+:17]=[N-:18].[Na+]>>[N:16]([CH2:2][C:3]1[CH:8]=[CH:7][C:6]([Si:9]([O:14][CH3:15])([O:12][CH3:13])[O:10][CH3:11])=[CH:5][CH:4]=1)=[N+:17]=[N-:18]

참가 물질

반응물 2

HCID 33557Sodium Azide

HCID 904924-(Chloromethyl)phenyltrimethoxysilane

생성물 1

HCID 20490159p-Azidomethylphenyltrimethoxysilane

반응 조건

온도: 150 °C

실험 절차

1.0 mole of p-chloromethylphenyltrimethoxysilane and 1.1 moles of sodium azide were heated in the presence of 5 mole percent of the catalyst described in Example 1 (a) for three hours under stirring at 150° C. Then the salt formed was separated and the subsequent distillation under reduced pressure gave the p-azidomethylphenyltrimethoxysilane in a yield of 89 weight percent with the following characteristics:

후처리

customThen the salt formed
customwas separated
distillationthe subsequent distillation under reduced pressure

출처 및 근거

ORD 기록: ord-7fe7420835bc4e11b7ca2ca2173caf0c
출처 데이터셋: uspto-grants-1983_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04401598

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