Salicyloyl chloride → HCID 178513857, 화합물

HRID 435735

반응식

HRID 435735 반응식
[Na+].[NH:2]1[CH:6]=[N:5][C:4]([C:7]([NH-:9])=[O:8])=[N:3]1.[C:10](Cl)(=[O:18])[C:11]1[C:12](=[CH:14][CH:15]=[CH:16][CH:17]=1)[OH:13]>C(#N)C>[C:10]([C:6]1[NH:2][N:3]=[C:4]([C:7]([NH2:9])=[O:8])[N:5]=1)(=[O:18])[C:11]1[C:12](=[CH:14][CH:15]=[CH:16][CH:17]=1)[OH:13]

참가 물질

4

반응물 2

HCID 74041Salicyloyl chlorideHCID 178514233HCID 178514233, 화합물

생성물 1

HCID 178513857HCID 178513857, 화합물

시약·촉매·용매 1

HCID 6342Acetonitrile용매

실험 절차

A 25 ml. portion of dry acetonitrile is added to a mixture of 1.3 g. of the s-triazole carboxamide sodium salt and 2 g. of salicyloyl chloride followed by a few pellets of 4A molecular sieves. The mixture is stirred at room temperature for 16 hours and then filtered through Celite. The colorless solid is obtained on evaporating the filtrate is washed with diethyl ether; yield, 1 g., m.p. 147°-150° C. (dec.). Its infrared spectrum is essentially the same as that obtained from the product in Example 7.

후처리

  1. filtrationfiltered through Celite
  2. customThe colorless solid is obtained
  3. customon evaporating the filtrate
  4. washis washed with diethyl ether
  5. customyield
  6. customthat obtained from the product in Example 7

출처 및 근거

ORD 기록
ord-fc5a8c5d9c524162bb776eeae08319f4
출처 데이터셋
uspto-grants-1977_02
특허 번호
US04006159

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