Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Trichloro(3-chloropropyl)silane → 3-(3-Chloropropyl)-1,1,1,5,5,5-hexamethyl-3-[(trimethylsilyl)oxy]trisiloxane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Trichloro(3-chloropropyl)silane | HCID 75693 | — |
| 반응물 | sodium trimethyl(oxido)silane | HCID 178504319 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | 3-(3-Chloropropyl)-1,1,1,5,5,5-hexamethyl-3-[(trimethylsilyl)oxy]trisiloxane | HCID 2757891 | — |
반응 단계
Gamma-chloropropyltrichlorosilane (21.2 g., 0.1 mole) is dissolved in 200 ml. of dry ether and an ether slurry of (33.6g, 0.3 mole) sodium trimethylsilanoate, (CH3)3SiONa, is added in small portions. The mixture is allowed to stand for 12 hours and is then refluxed for an additional 3 hours. Filtration of the sodium chloride and removal of the ether from the filtrate leaves gamma-chloropropyltris-trimethylsiloxysilane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04006176 |
| 출처 데이터셋 | uspto-grants-1977_02 |
| ORD ID | ord-4b95dbfdd839442b853566681648315a |
| 출처 메모 | uspto-grants-1977_02 |