Chlorotriethylsilane → 3-Triethylsilyl-2-oxazolidinone

반응식

[CH2:1]([Si:3]([CH2:7][CH3:8])([CH2:5][CH3:6])Cl)[CH3:2].[O:9]1[CH2:13][CH2:12][NH:11][C:10]1=[O:14]>>[CH2:1]([Si:3]([CH2:7][CH3:8])([CH2:5][CH3:6])[N:11]1[CH2:12][CH2:13][O:9][C:10]1=[O:14])[CH3:2]

참가 물질

반응물 2

HCID 13819Chlorotriethylsilane

HCID 739492-Oxazolidinone

생성물 1

HCID 214547763-Triethylsilyl-2-oxazolidinone

실험 절차

Following the previous example, but replacing the trimethylchlorosilane with triethylchlorosilane (63.3 g; 0.42 mol) and operating under similar conditions, the result is the compound of the above heading; a colourless fluid liquid, obtained with a similar yield. 2-oxazolidinone, calculated: 42.82%; found: 42.70%. Distils at 100° C between 2 and 4 mm.

후처리

customa colourless fluid liquid, obtained with a similar yield
customDistils at 100° C between 2 and 4 mm

출처 및 근거

ORD 기록: ord-ede3c3d0c1ca43f09684b307132c2b8e
출처 데이터셋: uspto-grants-1977_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04007168

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